Iridium-Catalyzed 1,3-Hydrogen Shift/Chlorination of Allylic Alcohols

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Iridium-Catalyzed 1,3-Hydrogen Shift/Chlorination of Allylic Alcohols**

Chlorinated compounds are among the most common and versatile building blocks in organic synthesis. Among these, achlorocarbonyl derivatives are of synthetic value owing to the variety of functional groups that can be introduced both at the chlorinated a-carbon atom and at the carbonyl functionality. For instance, they readily undergo substitution/addition reactions and cross-coupling reactions...

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ژورنال

عنوان ژورنال: Angewandte Chemie International Edition

سال: 2013

ISSN: 1433-7851

DOI: 10.1002/anie.201301013